Product ID:EASTMAN MPK (METHYL PROPYL KETONE)
MSDS Date:09/17/1999
FSC:6810
NIIN:01-459-1992
MSDS Number: CKHPL

EASTMAN CHEM PRODUCTS A SUB OF EASTMAN KODAK CO

WILCOX DR AND LINCOLN ST
KINGSPORT, TN 37662
US

Emergency Phone: 1-800-EASTMAN

Info Phone: 615-229-6094/2000

Preparer: EASTMAN PRODUCT SAFETY

Cage: 74364

EASTMAN CHEM PRODUCTS A SUB OF EASTMAN KODAK CO

KINGSPORT, TN 37662 US

Telephone: 423-229-2000

Cage: 74364

METHYL PROPYL KETONE

CAS: 107-87-9

RTECS: SA7875000

OSHA PEL 700 MG/M3;200 PPM

ACGIH TLV: 705 MG/M3;200 PPM

METHYL ISOBUTYL KETONE

CAS: 108-10-1

RTECS: SA9275000

OSHA PEL 410 MG/M3;100 PPM

ACGIH TLV: 205 MG/M3;50 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:LD50 (ORAL, RAT) 3.37G/KG
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: GENERAL: BASED ON
ANIMAL DATA AND STRUCTURE-ACTIVITY RELATIONSHIPS, THIS PRODUCT IS
NOT EXPECTED TO CAUSE NERVOUS SYSTEM DAMAGE. INHALATION: HIGH VAPOR
CONCENTRATIONS MAY CAUSE DR OWSINESS AND IRRITATION. EYES: HIGH
VAPOR CONCENTRATIONS MAY CAUSE IRRITATION. SKIN: EXPECTED TO BE A
LOW HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED
PERSONNEL. INGESTION: EXPECTED T O BE A LOW INGESTION HAZARD.
Explanation of Carcinogenicity:IARC: NOT LISTED. ACGIH: NOT LISTED.
NTP: NOT LISTED.
Effects of Overexposure:DROWSINESS, IRRITATION

First Aid:INHALATION: MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET
MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: IN CASE OF IRRITATION
FROM AIRBORNE EXPOSURE, MOVE TO FRESH AIR. IF EASY TO DO, REMOVE
CONTACT LE NSES. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. SKIN:
WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION: SEEK MEDICAL ADVICE.

Flash Point Method:TCC
Flash Point:=7.8C, 46.F
Autoignition Temp:=448.9C, 840.F
Lower Limits:(93F):1.56%
Upper Limits:(144F):8.7%
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE (CO2),
ALCOHOL FOAM
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL. WATER MAY BE INEFFECTIVE IN FIGHTING THE FIRE.
Unusual Fire/Explosion Hazard:FLAMMABLE. VAPORS MAY CAUSE A FLASH FIRE
OR IGNITE EXPLOSIVELY. VAPORS MAY TRAVEL CONSIDERABLE DISTANCE TO A
SOURCE OF IGNITION & FLASH BACK. PREVENT BUILDING OF VAPORS OR
GASES TO EXPLOSIVE CONCENTRA TIONS. MAY FORM PEROXIDES OF UNKNOWN
STABILITY.

Spill Release Procedures:USE PERSONAL PROTECTIVE EQUIPMENT.
ELIMINATESE ALL IGNITION SOURCES. ABSORB SPILL WITH VERMICULITE OR
OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE.
FOR LARGE SPILLS: USE WATER S PRAY TO DISPERSE VAPORS AND DILUTE
SPILL TO A NONFLAMMABLE MIXTURE. PREVENT RUNOFF FROM ENTERING
DRAINS, SEWERS, OR STREAMS.

Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP
CONTAINER IN A WELL-VENTILATED PLACE. AVOID BREATHING HIGH VAPOR
CONCENTRACTIONS. KEEP AWAY FROM HEATAND LIGHT. KEEP AWAY FROM
HEAT, SPARKS, AND FLAMES. KEEP FROM CONTACT WITH OXIDIZING
MATERIALS. USE ONLY WITH ADEQUATE VENTILATION.
Other Precautions:COMPLY WITH ALL NATIONAL STATE, AND LOCAL CODES
PERTAINING TO THE STORAGE, HANDLING, DISPENSING, AND DISPOSAL OF
FLAMMABLE LIQUIDS. MINIMIZE EXPOSURE TO AIR. IF PEROXIDE
FORMATION IS SUSPECTED, DO N OT OPEN OR MOVE CONTAINER. AVOID
BREATHING HIGH VAPOR CONCENTRATIONS. USE ONLY WITH AQEQUATE VENTIA
LTION.

Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED
RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: ORGANIC VAPOR. IF
RESPIRATORS ARE USED, A PROGR AM SHOULD BE INSTITUTED TO ASSURE
COMPLIANCE WITH OSHA STANDARD 63 FR 1152, JAN 8, 1998.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION OR OTHER CONTROLS.
Protective Gloves:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE
SKIN CONTACT.
Eye Protection:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE EYE
CONTACT.
Other Protective Equipment:EYE BATH, WASHING FACILITIES.
Work Hygienic Practices:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Supplemental Safety and Health
NO DATA PROVIDED BY RESPONSIBLE PARTY.

HCC:F2
Boiling Pt:=100.6C, 213.F
Melt/Freeze Pt:=-77.8C, -108.F
Vapor Pres:@20C (68F)37BAR(27.8MMHG)
Vapor Density:(AIR=1)2.9
Spec Gravity:@20C (68F)(H20=1):0.81
Evaporation Rate & Reference:(N-BUTYL ACETATE=1):2.3
Solubility in Water:MODERATE
Appearance and Odor:COLORLESS LIQUID - KETONE ODOR

Stability Indicator/Materials to Avoid:YES
MATERIAL CAN REACT VIOLENTLY WITH STRONG BASES, STRONG OXIDIZING
AGENTS, STRONG REDUCING AGENTS.
Stability Condition to Avoid:NORMALLY STABLE; HOWEVER, ON LONG TERM
STORAGE, MATERIALS CONTAINING SIMILAR FUNCTIONAL GROUPS FORM
PEROXIDES OF UNKNOWN STABILITY.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. MIX WITH COMPATIBLE CHEMICAL
WHICH IS LESS FALMMABLE AND INCINERATE. SINCE EMPTIED CONTAINERS
RETAIN PRODUCT RESIDUE , FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER
IS EMPTIED. RESIDUAL VAPORS MAY EXPLODE ON IGNITION; DO NOT CUT,
DRILL, GRIND/WELD ON OR NEAR CONTAINER.

Toxicological Information:INHALATION LC-50 (RAT): >2000 PPM/4 HOURS.
DERMAL LD-50 (RABBIT): 8 ML/KG. SUBCHRONIC TOXICITY DATA FOR METHYL
PROPYL KETONE: NO-OBSERVED-EFFECT LEVEL (NOEL) FOR NEUROTOXICITY =
305 PPM (ONLY CONCENTR ATION TESTED). ORAL STUDY (10 MONTHS, RAT):
LOWEST-OBSERVED-EFFECT LEVEL (LOEL) = 1% IN DRINKING WATER (REDUCED
BODY WEIGHT GAIN); NOEL = 0.5% IN DRINKING WATER.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:IT HAS THE FOLLOWING PROPERTIES: A HIGH BIOCHEMICAL OXYGEN
DEMAND AND A POTENTIAL TO CAUSE OXYGEN DEPLETION IN AQUEOUS
SYSTEMS, A LOW POTENTIAL TO AFFECT AQUATIC ORGANISMS, A HIGH
POTENTIAL TO BIODEGR ADE (LOW PERSISTANCE) WITH UNACCLIMATED
MICROORGANISMS FROM ACTIVATED SLUDGE. WHEN DILUTED WITH A LARGE
AMOUNT OF WATER, THIS MATERIAL RELEASED DIRECTLY OR INDIRECTLY INTO
THE ENVIRONMENT IS NOT EXPEC TED TO HAVE A SIGNIFICANT IMPACT.
OXYGEN DEMAND DATA: THOD: 2.6 G O2/G; COD: 1.8 G O2/G; BOD-5: 1.38
G O2/G; BOD-20: 1.8 G O2/G. ACUTE AQUATIC EFFECS: 96-H LC-50
(FATHEAD MINNOW): >1000 MICROLITER/L.

Transport Information:US DOT: REGULATED. CLASS III, PACKING GROUP II.
AIR, INTERNATIONAL CIVIL AVIATION ORGANIZATION (ICAO). -ICAO
STATUS: REGULATED. CLASS III, PACKING GROUP II. - SEA,
INTERNATIONAL MARITIME DANGEROUS GOO DS (IMDG): IMDG STATUS:
REGULATED, CLASS 3.2, PACKING GROUP II.

SARA Title III Information:CHEMICALS SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART
372: METHYL ISOBUTYL KETONE. SECTION 311 AND 312: FIRE HAZARD,
IMMEIDATE (ACUTE) HEALTH HAZARD.
Federal Regulatory Information:ALL COMPONENTS OF THIS PRODUCT ARE
LISTED ON THE TOXIC SUBSTANCE CONTROL ACT (TSCA) INVENTORY. ANY
IMPURITIES PRESENT IN THIS PRODUCT ARE EXEMPT FROM LISTING.
State Regulatory Information:CALIFORNIA PROPOSITION 65: NONE KNOWN TO
EASTMAN.